Tag Archives: ink pH testing

Loose Ends Ink Test

By on June 4, 2023
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While wrapping up our ink tests in 2021, we had a bunch of loose bottles of ink that we tested on the same pieces of Rhodia paper to save paper and space. I left these test samples in the window for six months, and Dawn and I calibrated and tested the pH on these samples at 75.6-degrees Fahrenheit and 50% humidity.

Check out how UV light effected our hodge-podge selection of ink by Sheaffer, DeAtramentis, Iroshizuku, Monteverde and Waterman

As always, we found the results interesting. However, these results are simply raw data. How the chemistry of the inks reacts to the chemistry of a pen’s ink sac or converter is not necessarily dictated by the pH level of the ink. For example: You’ll see below that Waterman Serenity Blue is very acidic with a pH at 2.7, but we’ve used it in vintage pens for years without it doing anything other than standard wear on ink sacs over 5 to 10 or more years. Many dealers other than myself find Waterman inks to be a gold standard of safety for use in vintage pens.

You can see in the photo that most of the ink fared poorly in the light-fast UV test. The Sheaffer inks were the Czech Republic-made variety in blue-black, blue and purple. Their colors are quite pretty when freshly dried. UV light makes the blue-black a faded black and grey. Blue fades badly to a blue-black, and the purple almost complete disappears!

De Atramentis Black Rose holds up reasonably well, though it fades a little. Red Rose fades by about 50%.

We had 2 leftover Iroshizuku inks. The green Fukurokuju is a lovely Irish mint of a color, but it fades really badly in UV light. I’m also a fan of the medium-grey Fuyu Syogun, which has hints of purple and blue. Unfortunately, it fades to almost invisible.

Up next were our first looks at bottled Monteverde ink. Blue Horizon and California Teal are both gorgeous. If you lay it down too wet, it has some nice sheening. Yet, the blue faded to purple and the teal turned grey! Monteverde Black faded heavily to a reddish-grey. Amazingly, Mandarin orange held its color really well. Napa Burgundy faded a bit but generally held its color better than most of the other Monteverde inks.

Last but not least was Waterman’s Serenity Blue. Just about every expert I know insists it is the same formula as Waterman’s Florida Blue, but I swear I see a change. Unfortunately, it behaves much like the old Florida Blue by fading pretty drastically in the sun.

Please look below for the pH readings on all of our inks tested. As a quick refresher, 0 to 6.9 is on the acid side of the scale, with 0 being the extremely corrosive end of the scale. 7 is pH neutral, like pure water. 7.1 to 14 is alkali or base, with 14 being the extremely corrosive side of that half of the scale. Again, our pH results don’t guarantee that the ink is corrosive in your pen, as the chemistry of the ink might mix differently with the chemistry of your ink sac or converters.

SHEAFFER:
Blue-Black                    4.5
Blue                                3.6
Purple                            5.1

IROSHIZUKU
Fukurokuju                   8.7
Fuyu Syogun                 9.6

MONTEVERDE
Horizon Blue                6.5
California Teal              7.4
Black                               4.4
Mandarin                       7.7
Napa Burgundy            6.9

WATERMAN
Serenity Blue                 2.7

De Atramentis Starts Rich and Fades

By on January 9, 2023
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Happy New Year! Let’s start the year right with a fresh look at some lesser known inks.

De Atramentis is the Latin word for ink. The company is based in Germany. It specializes in a series of specialty inks, including perfumed inks. We obtained 13 colors from a collection and decided to test them with 6 months of UV light. We also tested their pH level.

Here are the results of our UV light testing of De Atramentis inks. The left side is unexposed to UV light. The right side was in a sunny window for about 6 months.

The inks we tested were Black Rose, Red Rose, Gladiolus, Heather Violet, Elderberry, Lavender, Myrrhe, Field Flowers, Deepwater, Olive Green, Lily of the Valley, Tulip and Mozart.

Straight out of the bottle, I love the rich, vibrant, saturated colors of the inks. A blue-ink addict, I especially love the Myrrhe and Field Flowers. Lavender is lovely but it is a deep blue, not purple, as I would expect. Deepwater is a blue-black. Lily of the Valley stands out as a very pretty green, to me. Red Rose shades from reddish purple to a nice pinky-purple, fuchsia, maybe.

Click the photo for a close-up look at the DeAtramentis inks.

After spending most of autumn and winter in my sunniest window, the results surprised me. You can see the results in the photo, but there was a unique unevenness to how the colors handled the UV light. Most of them lost their special vibrant saturation. It always surprises me when black inks such as Black Rose fade a bit. Red rose took a hit but didn’t completely fade out the way Gladiolus and Heather Violet did. The deep, rich purple of Elderberry faded substantially but still held on. Lavendar, Myrrhe and Field Flowers faded heavily to what basically is the same color! Deepwater lost its blue to become more of a black. Yet Olive Green and Lily of the Valley didn’t lose much of their color or vibrancy at all! Tulip and Mozart seemed to have lost about half of their original color.

Vibrant and saturated colors often fare poorly on pH tests, as they are usually quite acidic or base/alkali. In our testing, the results were fairly pH neutral for these inks. As a brief reminder, pH neutral is 7 on the scale of 0 to 14. Pure distilled water is a 7. O is acidic and 14 is alkali or base. In theory, we want our inks as close to 7 as we can get them. BUT, it is important to note that we have no idea how the ingredients in these inks will interact with the rubber ink sacs, celluloid and elements of your converters. A 7 pH with ingredients that might cause some sort of chemical reaction with a rubber ink sac might be disastrous for a pen. Therefore, this is simply raw data that I hope you find interesting.

Black Rose………………….6.6
Red Rose…………………….6.6
Gladiolus…………………….5.8
Heather Violet…………….6.5
Elderberry…………………..7.0
Lavender…………………….4.7
Myrrhe……………………….4.5
Field Flowers………………4.7
Deepwater………………….6.8
Olive Green…………………7.4
Lily of the Valley…………4.4
Tulip………………………….6.0
Mozart……………………….5.4

Caran D’Ache Chromatics Face the UV-pH Challenge

By on September 6, 2022
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Swiss pen maker Caran D’Ache is most famous for its precision engineering on its line of ballpoint pens. They make nice fountain pens, too, but it is the company’s ballpoints that the world knows best. Yet, as so many pen makers now do, it also decided to enter the lucrative fountain pen ink market.

Here is a side-by-side comparison of Caran D’Ache Chromatic inks before and after undergoing 3 months of UV sunlight testing.

Caran D’Ache Chromatic Inks are a daring entry, indeed. From their hexagonal bottles that tip to fill to the last drop to their bright and cheery colors, Chromatics made an instant splash on the scene.

Naturally, we wanted to know how well these inks hold up to UV light from the sun and where they register on the scale of a pH test. We placed this sample in our sunniest window for 3 months. We also used our pH meter, which was calibrated to the heat and temperature of our testing station before testing the inks.

The results of our test were surprising. I falsely suspected that there might be some heavier pigmentation in the “Chromatic” inks that would make them shine and dazzle a bit on the page. However, virtually all of the ink colors lost seemingly 85 to 90% of their color, fading heavily from view. “Electric Orange” all but disappeared. Even a stalwart color such as “Cosmic Black” faded to a medium brown, and it had the most staying power.

The pH test results ranged all over the map. As a quick refresher on chemistry, a pH number of 7 is pH neutral like pure water. The closer to 0 something becomes the more acidic it is. The closer to 14 it goes, the more alkali or base something is. In theory, you want an ink that is pH neutral, BUT we have no idea how the chemicals in each ink will react to the chemicals of the ink sacs, converters, inkfeeds and the like. We have found some “neutral” inks to eat through ink sacs rapidly, while some seemingly alkali or acidic inks don’t bother a pen’s parts at all. The following is simply raw data for you to do with as you please.

COLOR:                              pH Score:
Cosmic Black                      6.9
Electric Orange                  8.9
Vibrant Green                     4.4
Idyllic Blue                          3.1
Infra Red                             8.2
Ultra Violet                         7.6
Magnetic Blue                    3.7
Organic Brown                   4.5
Hypnotic Turquoise         N/A

A few of the things that stand out to us are that Cosmic Black is almost perfectly neutral. Aligning with more of our past experiments, the blues were fairly acidic. Yet, playing against stereotype, the red and purple were closer to neutral. Green remains quite acidic, which is expected, but the brown also was acidic, which wasn’t expected.

As always, I hope you found this snippet of ink data helpful to your quest for the perfect ink for you.

Strong Enough for a Man; pH Balanced for a Fountain Pen?

By on September 1, 2021
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One of the many great aspects of marrying a scientist is the gadgetry. Intrigued by my ink-fast tests  with UV light, Dawn decided to get a professional pH meter to test our ink for corrosiveness. If you remember basic chemistry from high school…which I barely do…you will remember that we have acid on one side of a scale and base/alkali on the other. The scale ranges from 0 to 14. 7 is neutral like distilled water. The further you move away from 7 in either direction is more corrosive. The 0 side is acid and the 14 side is base/alkali.

You would think that all inks are hovering around a 7 to be safe in your pen and on paper. We certainly did.

Holy cats! We were wrong.

First you saw these Pelikan Edelstein inks in our UV ink fast test. Now we’re going back and checking their pH balance!

For years I told people…as I was told by many pen collectors and dealers before me…that you can always trust simple blue and black inks from the major pen manufacturers. However, just our initial testing indicates that might not be the best advice any longer.

Before I go on, let me preface the following by saying that we are not chemists. We feel confident in our results from our testing. However, we do not know the chemistry of the ink interacting with ink sacs, celluloid, gaskets, seals and other assemblies inside your pens. Our pH testing is simply raw data we gather from bottles of ink we have collected. Yet, it might help shed some light if you are experiencing trouble with certain inks interacting poorly with your vintage or modern pens over time.

Having recently written about Pelikan Edelstein inks in an ink-fast test, I thought I would revisit these inks for our pH testing. For those keeping score at home our meter and inks were tested and calibrated at 24ºC.

Pelikan Edelstein Amethyst               5.6
Pelikan Edelstein Aquamarine          3.3
Pelikan Edelstein Aventurine             6.4
Pelikan Edelstein Garnet                   6.5
Pelikan Edelstein Jade                       5.3
Pelikan Edelstein Olivine                    6.0
Pelikan Edelstein Ruby                       7.9
Pelikan Edelstein Sapphire                 3.7
Pelikan Edelstein Smokey Quartz       6.5
Pelikan Edelstein Tanzanite                7.3
Pelikan Edelstein Topaz                      6.4
Pelikan Old Version Violet                   2.7
Pelikan Modern Violet                         3.4
Pelikan Brilliant Red                           6.9

Again, I’m not a chemist, and I have not studied how these inks interact chemically with ink sacs and other pen parts.

That said, what really strikes me as fascinating is that the “traditionally safe” blues such as Sapphire and Aquamarine are really acidic. I love Edelstein Sapphire and use it more than any of these other colors, and I would never have guessed it was as acidic at it is.

Also fascinating, I’ve been told for years never to put red ink in an ink sac, but Garnet, Ruby and Brilliant Red are among the closest inks to test near pH neutral.

Again, the chemicals in the ink might interact differently with the chemical compositions of our pens, but we find this to be a really fun look into our favorite inks. Many more UV and pH tests to come!